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Yes, you can substitute them in a pinch, but the measurements are key. Baking soda is much stronger, about 3 to 4 times more than baking powder. So, for 1 tsp of baking soda, you’d need to use 3 tsp of baking powder. But be careful! Using the wrong amount can stop your cake from rising. Too much baking soda gives a bitter, soapy taste, while excess baking powder can leave a metallic aftertaste.